Open AccessStepwise oxidation of three communicating metal centres: electrochemistry of trinuclear trindenyl complexes of manganese or rhodium
Author(s) -
Rainer F. Winter,
David T. Pierce,
William E. Geiger,
Thomas J. Lynch
Publication year - 1994
Publication title -
journal of the chemical society chemical communications
Language(s) - English
Resource type - Journals
eISSN - 2050-5639
pISSN - 0022-4936
DOI - 10.1039/c39940001949
Subject(s) - rhodium , manganese , chemistry , electrochemistry , metal , ligand (biochemistry) , inorganic chemistry , catalysis , electrode , organic chemistry , biochemistry , receptor
Trinuclear manganese or rhodium complexes of the trindenyl (Td) ligand undergo three separate 1 e–-oxidation reactions, with an abnormally large separation in potentials between the second and third oxidations of [Td{Rh3(cod)3}]
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