Hemilabile P,O-ligands in palladium catalysed C–C linkages: codimerization of ethylene and styrene and cooligomerization of ethylene and carbon monoxide | Zendy

George J. P. Britovsek | Zendy; Wilhelm Keim | Zendy; Stefan Mecking | Zendy; Daniel Sainz | Zendy; Trixie Wagner | Zendy

Open Access

Hemilabile P,O-ligands in palladium catalysed C–C linkages: codimerization of ethylene and styrene and cooligomerization of ethylene and carbon monoxide

Author(s) -

George J. P. Britovsek,

Wilhelm Keim,

Stefan Mecking,

Daniel Sainz,

Trixie Wagner

Publication year - 1993

Publication title -

journal of the chemical society chemical communications

Language(s) - English

Resource type - Journals

eISSN - 2050-5639

pISSN - 0022-4936

DOI - 10.1039/c39930001632

Subject(s) - ethylene , carbon monoxide , styrene , cationic polymerization , palladium , chemistry , catalysis , denticity , polymer chemistry , alkene , crystal structure , medicinal chemistry , photochemistry , organic chemistry , copolymer , polymer

Neutral and cationic palladium allyl complexes with bidentate ligands Ph2P(CH2)nCO2–(n= 1–3; X-ray crystal structure determination for complexes with n= 1 and 2) or Ph2P(CH2)nCO2R (n= 1–3; R = Me, Et) have been prepared and used as catalysts for the codimerization of ethylene and styrene and for the Cooligomerization of ethylene and carbon monoxide.

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