Coordinative stabilization of a phosphido-phosphinidene ligand
Author(s) -
Otto J. Scherer,
Rainer F. Winter,
Gotthelf Wolmershäuser
Publication year - 1993
Publication title -
journal of the chemical society chemical communications
Language(s) - English
Resource type - Journals
eISSN - 2050-5639
pISSN - 0022-4936
DOI - 10.1039/c39930000313
Subject(s) - phosphinidene , ligand (biochemistry) , chemistry , derivative (finance) , stereochemistry , crystallography , receptor , business , biochemistry , finance
The phosphido-phosphinidene coordination mode Cof a P2 ligand has been realized in the trinuclear complex [(TaL)3(P4)(P2)]2(L = 1,3-But2C5H3); structural proof was obtained by X-ray structure determination of the [(TaL)3(P4{Fe(CO)4}MP2)] derivative 3
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