Conversion of the cluster core structure via CO elimination and activation of the coordinated hydrocarbon ligand. Synthesis and reactions of WOs3Cp(CO)10(CMeCMeCCPh) | Zendy

Yün Chi | Zendy; Hui-Ying Hsu | Zendy; ShieMing Peng | Zendy; GeneHsiang Lee | Zendy

Open Access

Conversion of the cluster core structure via CO elimination and activation of the coordinated hydrocarbon ligand. Synthesis and reactions of WOs3Cp(CO)10(CMeCMeCCPh)

Author(s) -

Yün Chi,

Hui-Ying Hsu,

ShieMing Peng,

GeneHsiang Lee

Publication year - 1991

Publication title -

journal of the chemical society chemical communications

Language(s) - English

Resource type - Journals

eISSN - 2050-5639

pISSN - 0022-4936

DOI - 10.1039/c39910001023

Subject(s) - chemistry , thermal decomposition , cluster (spacecraft) , ligand (biochemistry) , toluene , yield (engineering) , hydride , decomposition , hydrocarbon , stereochemistry , medicinal chemistry , crystallography , metal , organic chemistry , materials science , biochemistry , receptor , computer science , metallurgy , programming language

[[abstract]]Reaction of WCp(CO)3C = CPh with Os3(CO)10(C2Me2) produced the butterfly cluster WOs3Cp(CO)10(CMeCMeCCPh) 1 in moderate yield; treatment of 1 with Me3NO followed by thermolysis in refluxing toluene yielded the spiked triangular cluster WOs3Cp(CO)9(mu-H)[CMeCMeCC(mu-2-eta-2-C6H4)] 3 as a major product; on further thermolysis, complex 3 reconverted to a butterfly cluster WOs3Cp(CO)9[CMeCMeCHC(mu-2-eta-2-C6H4)] 5 and then to a tetrahedral cluster WOs3Cp(CO)8[CMeCMeCHC(mu-2-eta-2-C6H4)] 6 via hydride migration followed by loss of CO; the structures of complexes 3, 5 and 6 have been determined by X-ray diffraction.[[fileno]]2010302010073[[department]]化學

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