The formation and stability of molybdenum–antimony and tungsten–antimony ternary oxides Sb2MO6, Sb2M2O9, Sb2Mo3O12 and Sb4MO9 in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies | Zendy

Ekaterina A. Berezovskaya | Zendy; E. Milke | Zendy; Michael Binnewies | Zendy

Open Access

The formation and stability of molybdenum–antimony and tungsten–antimony ternary oxides Sb2MO6, Sb2M2O9, Sb2Mo3O12 and Sb4MO9 in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies

Author(s) -

Ekaterina A. Berezovskaya,

E. Milke,

Michael Binnewies

Publication year - 2012

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c2dt31058a

Subject(s) - antimony , ternary operation , molybdenum , tungsten , mass spectrometry , quantum chemical , chemistry , analytical chemistry (journal) , molecule , phase (matter) , chemical stability , inorganic chemistry , organic chemistry , chromatography , computer science , programming language

The ternary oxides Sb(2)MO(6), Sb(2)M(2)O(9), Sb(4)MO(9) (M = Mo, W) and Sb(2)Mo(3)O(12) were detected in the gas phase by means of mass spectrometry (MS). These gaseous oxides are reported for the first time. Thermodynamic data was obtained experimentally and confirmed by quantum chemical (QC) calculations. In addition, structural data on these molecules was obtained. The ionisation potentials (IP) were also determined both experimentally and theoretically.

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