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Effect of dissolved LiCl on the ionic liquid–Au(111) electrical double layer structure
Author(s) -
Robert Hayes,
Natalia Borisenko,
Brendan Corr,
Grant B. Webber,
Frank Endres,
Rob Atkin
Publication year - 2012
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c2cc35737b
Subject(s) - ionic liquid , layering , ionic bonding , layer (electronics) , ion , double layer (biology) , materials science , chemistry , inorganic chemistry , chemical physics , analytical chemistry (journal) , chromatography , nanotechnology , organic chemistry , botany , biology , catalysis
The electrical double layer at ionic liquid (IL)-Au(111) interfaces is composed of alternating ion layers. Interfacial layering is markedly weaker when small amounts of LiCl are dissolved in the IL for all potential between -2.0 V and +2.0 V (vs. Pt). This means that models developed for pure IL electrical double layers may not be valid when solutes are present.

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