Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents | Zendy

Herbert C. Hoffmann | Zendy; Silvia Paasch | Zendy; Philipp Müller | Zendy; Irena Senkovska | Zendy; Mohan Padmanaban | Zendy; Frank Glorius | Zendy; Stefan Kaskel | Zendy; Eike Brunner | Zendy

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Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

Author(s) -

Herbert C. Hoffmann,

Silvia Paasch,

Philipp Müller,

Irena Senkovska,

Mohan Padmanaban,

Frank Glorius,

Stefan Kaskel,

Eike Brunner

Publication year - 2012

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c2cc35366k

Subject(s) - enantioselective synthesis , spectroscopy , metal organic framework , nuclear magnetic resonance spectroscopy , solid state nuclear magnetic resonance , solid state , chemistry , metal , combinatorial chemistry , materials science , computational chemistry , organic chemistry , catalysis , nuclear magnetic resonance , physics , adsorption , quantum mechanics

Recently, we have described the synthesis of chiral metal-organic frameworks iPr-ChirUMCM-1 and Bn-ChirUMCM-1 and their use in enantioselective separation. Here, we demonstrate for the first time the use of a chiral solvating agent (1-phenyl-2,2,2-trifluoroethanol, TFPE) for chiral recognition in iPr-ChirUMCM-1 and Bn-ChirUMCM-1 by means of solid-state(13)C NMR spectroscopy.

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