Polymer precursors from catalytic reactions of natural oils | Zendy

Marc R. L. Furst | Zendy; Ronan Le Goff | Zendy; Dorothee Quinzler | Zendy; Stefan Mecking | Zendy; Catherine H. Botting | Zendy; David J. ColeHamilton | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Polymer precursors from catalytic reactions of natural oils

Author(s) -

Marc R. L. Furst,

Ronan Le Goff,

Dorothee Quinzler,

Stefan Mecking,

Catherine H. Botting,

David J. ColeHamilton

Publication year - 2011

Publication title -

green chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.221

H-Index - 221

eISSN - 1463-9270

pISSN - 1463-9262

DOI - 10.1039/c1gc16094j

Subject(s) - catalysis , benzene , chemistry , organic chemistry , rapeseed , polymer , polymer chemistry , food science

Dimethyl 1,19-nonadecanedioate is produced from the methoxycarbonylation of commercial olive, rapeseed or sunflower oils in the presence of a catalyst derived from [Pd2(dba)3], bis(ditertiarybutylphosphinomethyl)benzene (BDTBPMB) and methanesulphonic acid (MSA). The diester is then hydrogenated to 1,19-nonadecanediol using Ru/1,1,1-tris-(diphenylphosphinemethyl)ethane (triphos). 1,19-Nonadecadienoic acid is hydrogenated to short chain oligoesters, which can themselves be hydrogenated to 1,19-nonadecanol by hydrogenation in the presence of water.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research