Enzyme-based biohybrid foams designed for continuous flow heterogeneous catalysis and biodiesel production
Author(s) -
Nicolas Brun,
Annick Babeau-Garcia,
MarieFrance Achard,
Clément Sánchez,
Fabien Durand,
Guillaume Laurent,
Marc Birot,
Hervé Deleuze,
Rénal Backov
Publication year - 2011
Publication title -
energy and environmental science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 14.486
H-Index - 343
eISSN - 1754-5706
pISSN - 1754-5692
DOI - 10.1039/c1ee01295a
Subject(s) - catalysis , biodiesel production , transesterification , biodiesel , materials science , enzyme catalysis , steric effects , continuous flow , chemical engineering , immobilized enzyme , covalent bond , chemistry , organic chemistry , enzyme , biochemical engineering , engineering
5 pagesInternational audienceThe one-pot synthesis and use of monolithic biohybrid foams in a continuous flow device reported in here presents the advantages of covalent stabilization of the enzymes, together with a low steric hindrance between proteins and substrates, optimized mass transport due to the interconnected macroporous network and simplicity with regard to the column in situ synthetic path. Those features, when applied to transesterification (biodiesel production) via enzyme catalysis, provide among the top enzymatic activities displayed by biohybrid catalysts bearing unprecedented endurance of continuous catalysis for a two month period
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