Anion polarity-induced dual oxidation states in a dual-layered purely organic paramagnetic charge-transfer salt, (TTF)3(PO-CON(CH3)C2H4SO3)2, where PO = 2,2,5,5-tetramethyl-3-pyrrolin-1-oxyl free radical | Zendy

Hiroki Akutsu | Zendy; Atsushi Kawamura | Zendy; J. Yamada | Zendy; Shin’ichi Nakatsuji | Zendy; Scott S. Turner | Zendy

Open Access

Anion polarity-induced dual oxidation states in a dual-layered purely organic paramagnetic charge-transfer salt, (TTF)3(PO-CON(CH3)C2H4SO3)2, where PO = 2,2,5,5-tetramethyl-3-pyrrolin-1-oxyl free radical

Author(s) -

Hiroki Akutsu,

Atsushi Kawamura,

J. Yamada,

Shin’ichi Nakatsuji,

Scott S. Turner

Publication year - 2011

Publication title -

crystengcomm

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.813

H-Index - 132

ISSN - 1466-8033

DOI - 10.1039/c1ce05578j

Subject(s) - paramagnetism , ion , chemistry , salt (chemistry) , anisotropy , spins , charge (physics) , polarity (international relations) , crystallography , condensed matter physics , organic chemistry , physics , biochemistry , cell , quantum mechanics

The purely organic paramagnetic charge-transfer salt (TTF)3(PO-CON(CH3)C2H4SO3)2 was prepared. The anisotropic anion forms a head-to-head arrangement in the anionic layer, giving dual donor layers with different oxidation states. SQUID magnetometry indicates that spins are localized not only on the free radical (PO) but also on both TTF layers.

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