Photosensitizing catalysis of the B12 complex without an additional photosensitizer | Zendy

Hisashi Shimakoshi | Zendy; Li Li | Zendy; Masashi Nishi | Zendy; Yoshio Hisaeda | Zendy

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Photosensitizing catalysis of the B12 complex without an additional photosensitizer

Author(s) -

Hisashi Shimakoshi,

Li Li,

Masashi Nishi,

Yoshio Hisaeda

Publication year - 2011

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c1cc12482j

Subject(s) - triethanolamine , cobalamin , photochemistry , photosensitizer , chemistry , catalysis , ionic liquid , perchlorate , derivative (finance) , irradiation , ionic bonding , vitamin b12 , organic chemistry , ion , analytical chemistry (journal) , biochemistry , physics , nuclear physics , financial economics , economics

A cobalamin derivative, heptamethyl cobyrinate perchlorate, was activated by UV light irradiation to form a Co(I) species in the presence of triethanolamine and used for a dechlorination reaction, and this photochemical reaction was accelerated in an ionic liquid.

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