Open AccessNovel heterobimetallic ruthenium(iii)–cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]− (Q = 8-quinolinolato): synthesis, structures and magnetic properties
Author(s) -
Jing Xiang,
Lihui Jia,
WaiLun Man,
Qian Kang,
GeneHsiang Lee,
ShieMing Peng,
Song Gao,
TaiChu Lau
Publication year - 2011
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c1cc12446c
Subject(s) - ruthenium , cobalt , chemistry , crystallography , combinatorial chemistry , inorganic chemistry , catalysis , organic chemistry
Reaction of [Ru(II)(PPh(3))(3)Cl(2)] with HQ and KCN produces a new dicyanoruthenium(III) building block, [Ru(III)(Q)(2)(CN)(2)](-). It reacts with hydrated CoCl(2) in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3.
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