First metal complexes of 6,6′-dihydroxy-2,2′-bipyridine: from molecular wires to applications in carbonylation catalysis | Zendy

Christopher M. Conifer | Zendy; Russell A. Taylor | Zendy; David J. Law | Zendy; Glenn J. Sunley | Zendy; Andrew J. P. White | Zendy; George J. P. Britovsek | Zendy

Open Access

First metal complexes of 6,6′-dihydroxy-2,2′-bipyridine: from molecular wires to applications in carbonylation catalysis

Author(s) -

Christopher M. Conifer,

Russell A. Taylor,

David J. Law,

Glenn J. Sunley,

Andrew J. P. White,

George J. P. Britovsek

Publication year - 2010

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c0dt01526a

Subject(s) - carbonylation , catalysis , bipyridine , rhodium , ligand (biochemistry) , chemistry , methyl acetate , metal , solid state , polymer chemistry , crystallography , organic chemistry , carbon monoxide , crystal structure , receptor , biochemistry

The first square planar rhodium(I) complexes containing the 6,6'-dihydroxy-2,2'-bipyridine ligand have been prepared. The complexes form molecular wires in the solid state and are active catalysts for the carbonylation of methyl acetate.

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