In situ observation and mechanistic elucidation of metastable colored species in crystalline state photochromism of trans-biindenylidenedione | Zendy

Kotaro Fujii | Zendy; K. Aruga | Zendy; Akiko Sekine | Zendy; Hidehiro Uekusa | Zendy; K. Sohno | Zendy; Koichi Tanaka | Zendy

Open Access

In situ observation and mechanistic elucidation of metastable colored species in crystalline state photochromism of trans-biindenylidenedione

Author(s) -

Kotaro Fujii,

K. Aruga,

Akiko Sekine,

Hidehiro Uekusa,

K. Sohno,

Koichi Tanaka

Publication year - 2010

Publication title -

crystengcomm

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.813

H-Index - 132

ISSN - 1466-8033

DOI - 10.1039/c0ce00642d

Subject(s) - photochromism , metastability , colored , in situ , photochemistry , chemical physics , chemistry , crystal (programming language) , reaction mechanism , solid state , materials science , crystallography , organic chemistry , catalysis , computer science , composite material , programming language

A metastable colored species from the photochromic reaction of trans-biindenylidenedione, which only proceeds in the crystalline state, has been directly observed by in situ crystal structure analysis method. The reaction mechanism and observed color change have also been confirmed from the theoretical calculation and the spectral measurement

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