An amino-modified Zr-terephthalate metal–organic framework as an acid–base catalyst for cross-aldol condensation | Zendy

Frederik Vermoortele | Zendy; Rob Ameloot | Zendy; Alexandré Vimont | Zendy; Christian Serre | Zendy; Dirk De Vos | Zendy

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An amino-modified Zr-terephthalate metal–organic framework as an acid–base catalyst for cross-aldol condensation

Author(s) -

Frederik Vermoortele,

Rob Ameloot,

Alexandré Vimont,

Christian Serre,

Dirk De Vos

Publication year - 2010

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c0cc03038d

Subject(s) - aldol condensation , benzaldehyde , heptanal , catalysis , lewis acids and bases , aldol reaction , metal organic framework , base (topology) , condensation , metal , chemistry , organic chemistry , polymer chemistry , materials science , aldehyde , adsorption , mathematical analysis , physics , mathematics , thermodynamics

After controlled pretreatment, some Zr-terephthalate metal-organic frameworks are highly selective catalysts for the cross-aldol condensation between benzaldehyde and heptanal. The proximity of Lewis acid and base sites in the amino-functionalized UiO-66(NH(2)) material further raises the reaction yields.

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