Synthesis of a 1-boratabenzene-(2,3,4,5-tetramethylphosphole): towards a planar monophosphole
Author(s) -
Guillaume BélangerChabot,
P. Rioux,
Laurent Maron,
FrédéricGeorges Fontaine
Publication year - 2010
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c0cc01999b
Subject(s) - phosphole , aromaticity , planar , crystallography , density functional theory , chemistry , stereochemistry , computational chemistry , molecule , organic chemistry , computer science , computer graphics (images)
Novel boratabenzene-phosphole complexes have been prepared and structurally characterized. The electronic communication between the two heterocyclic rings linked by a P-B bond and the aromaticity of these systems were probed using crystallographic and density functional studies.
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