Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages | Zendy

Takuya Shiga | Zendy; Graham N. Newton | Zendy; Jennifer S. Mathieson | Zendy; Tamaki Tetsuka | Zendy; Masayuki Nihei | Zendy; Leroy Cronin | Zendy; Hiroki Oshio | Zendy

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Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages

Author(s) -

Takuya Shiga,

Graham N. Newton,

Jennifer S. Mathieson,

Tamaki Tetsuka,

Masayuki Nihei,

Leroy Cronin,

Hiroki Oshio

Publication year - 2010

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/b925399h

Subject(s) - chemistry , enantiomer , adamantane , cyanide , circular dichroism , crystallography , tetraethylammonium , chirality (physics) , stereochemistry , inorganic chemistry , chiral symmetry , organic chemistry , potassium , physics , quark , quantum mechanics , nambu–jona lasinio model

Enantiomeric, ferromagnetically coupled decanuclear {Ni₆Fe₄} cages with adamantane-like cores were synthesized around templating tetraethylammonium cations, as shown by crystallographic analysis and CSI-MS, and their homochiral nature was confirmed by circular dichroism measurements.

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