The commensurate modulated structure of the metastable state in spin crossover complex [Fe(abpt)2(NCS)2] | Zendy

ChouFu Sheu | Zendy; SzuMiao Chen | Zendy; Shih-Chi Wang | Zendy; GeneHsiang Lee | Zendy; YiHung Liu | Zendy; Yu Wang | Zendy

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The commensurate modulated structure of the metastable state in spin crossover complex [Fe(abpt)2(NCS)2]

Author(s) -

ChouFu Sheu,

SzuMiao Chen,

Shih-Chi Wang,

GeneHsiang Lee,

YiHung Liu,

Yu Wang

Publication year - 2009

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/b910378c

Subject(s) - spin crossover , metastability , condensed matter physics , spin (aerodynamics) , materials science , spin states , crossover , state (computer science) , crystallography , chemistry , physics , thermodynamics , organic chemistry , algorithm , artificial intelligence , computer science

Two new polymorphs (C and D) of [t-Fe(abpt)(2)(NCS)(2)] are characterized, a commensurate modulated structure with the c axis tripled in the thermally quenched metastable high spin state at 25 K is found in polymorph C.

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