Fluorescent protein red Kaede chromophore; one-step, high-yield synthesis and potential application for solar cells
Author(s) -
WeiTi Chuang,
BoSo Chen,
KewYu Chen,
ChengChih Hsieh,
PiTai Chou
Publication year - 2009
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/b908542d
Subject(s) - chromophore , green fluorescent protein , fluorescence , chemistry , imidazole , yield (engineering) , condensation , photochemistry , materials science , organic chemistry , biochemistry , optics , physics , metallurgy , gene , thermodynamics
The one-step condensation between the Green Fluorescence Protein (GFP) chromophore and 1H-imidazole-5-carbaldehyde catalyzed by ZnCl(2) proved to be a facile method to synthesize the red Kaede chromophore and its derivatives (1a-d, 2, and 3 > 70%), among which 1a then demonstrated its potential as a dye in solar cell, with a moderate conversion efficiency (eta) of 3.04%.
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