Selective sensor utilizing a thin monolayer of b-oriented silicalite-1 crystals–magneto-elastic ribbon assembly
Author(s) -
Leszek Góra,
Jelan Kuhn,
Theodoros Baimpos,
Vladimiros Nikolakis,
Freek Kapteijn,
Ewa M. Serwicka
Publication year - 2009
Publication title -
the analyst
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.998
H-Index - 153
eISSN - 1364-5528
pISSN - 0003-2654
DOI - 10.1039/b905039f
Subject(s) - metglas , butane , materials science , ribbon , monolayer , adsorption , zeolite , layer (electronics) , coating , crystal (programming language) , diffraction , selectivity , analytical chemistry (journal) , chemical engineering , composite material , nanotechnology , optics , chemistry , organic chemistry , alloy , catalysis , physics , engineering , computer science , programming language , amorphous metal
This report presents the development of new selective gas sensors utilizing a b-oriented silicalite-1 layer-magneto-elastic ribbon assembly. The key principle for the operation of these sensors is monitoring the changes in the resonance frequency of the Metglas strip in relation to the concentration of a component in the gas phase. This technique provides a simple way for monitoring the effects of the amount of adsorbed gases in the silicalite-1 coating. The thickness of the zeolite layer is that of a single crystal. The silicalite-1 crystals are oriented in the b-direction, meaning that the straight channels are perpendicular to the sensor surface, which is confirmed by X-ray diffraction (XRD) analysis. The sensor was able to repeatedly sense carbon dioxide in air and could discriminate between linear and branched hydrocarbons. The sensor was able to detect n-butane, while it did not respond to the presence of iso-butane, indicating sensing selectivity.
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