Clear evidence of electron delocalization: synthesis, structure, magnetism, EPR and DFT calculation of the asymmetric hexanickel string complex containing a single mixed-valence (Ni2)3+ unit | Zendy

Isiah PoChun Liu | Zendy; ChiFen Chen | Zendy; ShaoAn Hua | Zendy; Chi-Hui Chen | Zendy; Hui-Ting Wang | Zendy; GeneHsiang Lee | Zendy; ShieMing Peng | Zendy

Open Access

Clear evidence of electron delocalization: synthesis, structure, magnetism, EPR and DFT calculation of the asymmetric hexanickel string complex containing a single mixed-valence (Ni2)3+ unit

Author(s) -

Isiah PoChun Liu,

ChiFen Chen,

ShaoAn Hua,

Chi-Hui Chen,

Hui-Ting Wang,

GeneHsiang Lee,

ShieMing Peng

Publication year - 2009

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/b901675a

Subject(s) - electron paramagnetic resonance , delocalized electron , magnetism , valence (chemistry) , chemistry , electron delocalization , crystallography , valence electron , electron , physics , condensed matter physics , nuclear magnetic resonance , quantum mechanics , organic chemistry

This paper describes the physical properties of the (Ni(2))(3+) mixed-valence unit that is an excellent conductivity-enhanced tool for metal string complexes.

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