Diffusion-based studies on the self-stacking and nanorod formation of platinum(ii) intercalators | Zendy

Anwen M. KrauseHeuer | Zendy; Nial J. Wheate | Zendy; William S. Price | Zendy; Janice R. AldrichWright | Zendy

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Diffusion-based studies on the self-stacking and nanorod formation of platinum(ii) intercalators

Author(s) -

Anwen M. KrauseHeuer,

Nial J. Wheate,

William S. Price,

Janice R. AldrichWright

Publication year - 2009

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/b820584a

Subject(s) - nanorod , platinum , stacking , intercalation (chemistry) , diffusion , metal , pulsed field gradient , materials science , chemistry , nuclear magnetic resonance , chemical physics , nanotechnology , inorganic chemistry , organic chemistry , physics , thermodynamics , catalysis

Pulsed gradient spin-echo nuclear magnetic resonance diffusion measurements have been used to show that platinum(II)-based intercalating agents self-stack in solution and form nanorods 0.45-3.9 nm in length (at 25 mM); their lengths are dependent on metal complex concentration, salt concentration and solution temperature.

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