Influence of a diene impurity on the molecular structure of phosphate-containing polymers with medical applications | Zendy

Lisbeth Grøndahl | Zendy; Shuko Suzuki | Zendy; Edeline WentrupByrne | Zendy

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Influence of a diene impurity on the molecular structure of phosphate-containing polymers with medical applications

Author(s) -

Lisbeth Grøndahl,

Shuko Suzuki,

Edeline WentrupByrne

Publication year - 2008

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/b803223h

Subject(s) - polymer , diene , impurity , monomer , phosphate , polymer chemistry , chemistry , materials science , molecule , chemical engineering , organic chemistry , natural rubber , engineering

We have demonstrated that the unacknowledged presence of almost 30% diene impurity in some commercial phosphate monomers had not only a significant effect on the molecular structure (topology) of a series of synthesized polymers but the instability of the ester functionalities during these polymerizations resulted in unexpectedly complex co-polymer chemistry.

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