Open AccessNew supramolecular isomers with 2D 44 square-grid and 3D 65·8 frameworks in a one-pot synthesis; reversible solvent uptake and intriguing luminescence properties
Author(s) -
ChihChieh Wang,
Wei-Zeng Lin,
Weiting Huang,
Mei-Ju Ko,
GeneHsiang Lee,
MeiLin Ho,
ChunWei Lin,
ChunWei Shih,
PiTai Chou
Publication year - 2008
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/b716953a
Subject(s) - luminescence , supramolecular chemistry , solvent , desorption , adsorption , square (algebra) , grid , materials science , chemistry , crystallography , organic chemistry , crystal structure , optoelectronics , mathematics , geometry
Two supramolecular isomers of [Ni(4-bpd)(2)(NCS)(2)] (4-bpd = 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene) with 2D 4(4) square-grid and 3D 6(5).8 frameworks are co-crystallized in a one-pot reaction, both of which exhibit interesting luminescence properties and reversible adsorption-desorption with respect to guest solvents.
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