Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative | Zendy

Thibault Cantat | Zendy; Frédéric Biaso | Zendy; Aurélien Momin | Zendy; Louis Ricard | Zendy; Michel Geoffroy | Zendy; Nicolas Mézailles | Zendy; Pascal Le Floch | Zendy

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Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative

Author(s) -

Thibault Cantat,

Frédéric Biaso,

Aurélien Momin,

Louis Ricard,

Michel Geoffroy,

Nicolas Mézailles,

Pascal Le Floch

Publication year - 2007

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/b715380e

Subject(s) - alkene , electron paramagnetic resonance , chemistry , derivative (finance) , radical ion , ion , ligand (biochemistry) , reduction (mathematics) , photochemistry , medicinal chemistry , combinatorial chemistry , organic chemistry , nuclear magnetic resonance , physics , receptor , biochemistry , financial economics , economics , catalysis , geometry , mathematics

A new type of stable radical ligand featuring a 1,1-bis-phosphinosulfide alkene backbone has been prepared and characterized on the basis of X-ray diffraction, EPR and DFT studies.

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