New palladium catalysed reactions of bromoporphyrins: synthesis and crystal structures of nickel(ii) complexes of primary 5-aminoporphyrin, 5,5′-bis(porphyrinyl) secondary amine, and 5-hydroxyporphyrin | Zendy

Louisa J. Esdaile | Zendy; Mathias O. Senge | Zendy; Dennis P. Arnold | Zendy

Open Access

New palladium catalysed reactions of bromoporphyrins: synthesis and crystal structures of nickel(ii) complexes of primary 5-aminoporphyrin, 5,5′-bis(porphyrinyl) secondary amine, and 5-hydroxyporphyrin

Author(s) -

Louisa J. Esdaile,

Mathias O. Senge,

Dennis P. Arnold

Publication year - 2006

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/b608365j

Subject(s) - palladium , amine gas treating , primary (astronomy) , chemistry , hydrazine (antidepressant) , nickel , catalysis , crystal structure , medicinal chemistry , polymer chemistry , organic chemistry , physics , astronomy , chromatography

Primary aminoporphyrin, secondary bis(porphyrinyl)amine and hydroxyporphyrin complexes have been isolated and characterised both spectroscopically and crystallographically from the reaction of 5-bromo-10,15,20-triphenylporphyrinatonickel(ii) with hydrazine under palladium catalysis.

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