Coupling of alkynols and a phenyl group to a novel η5-dihydronaphthalenide ligand on a ruthenium template | Zendy

J. Cubrilo | Zendy; Rainer F. Winter | Zendy; Dietrich Gudat | Zendy

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Coupling of alkynols and a phenyl group to a novel η⁵-dihydronaphthalenide ligand on a ruthenium template

Author(s) -

J. Cubrilo,

Rainer F. Winter,

Dietrich Gudat

Publication year - 2004

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/b412052c

Subject(s) - ruthenium , tetraphenylborate , ligand (biochemistry) , stoichiometry , coupling (piping) , methylene , chemistry , group (periodic table) , combinatorial chemistry , sodium tetraphenylborate , coupling reaction , medicinal chemistry , organic chemistry , materials science , catalysis , ion , biochemistry , receptor , metallurgy

We report the highly selective assembly of unprecedented eta5-1-methylene-1,2-dihydronaphthalenide ligands from the stoichiometric coupling of a phenyl group and two equivalents of disubstituted propargylic alcohols; in this reaction, tetraphenylborate acts as a phenylating agent.

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