Open AccessSynthesis of 13C-labelled, bicyclic mimetics of natural enediynes
Author(s) -
Parthasarathi Das,
Takashi Mita,
Martin J. Lear,
Masahiro Hirama
Publication year - 2002
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/b208939d
Subject(s) - enediyne , bicyclic molecule , chemistry , combinatorial chemistry , stereochemistry
Using a versatile synthesis with 13CH3PPh3I and CH(3)13CO2Et as 13C sources, the first examples of nine-membered chromophores which have been differentially labelled with 13C in their carbocyclic enediyne cores are described.
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