Experimental and computational investigations of phosphine exchange in 15-electron [CrCpCl2(PR3)] systems by stopped-flow and density functional calculations: a single-state SN2 mechanism
Author(s) -
Edmond Collange,
David Duret,
Rinaldo Poli
Publication year - 1999
Publication title -
journal of the chemical society. dalton transactions
Language(s) - English
Resource type - Journals
eISSN - 2050-5671
pISSN - 0300-9246
DOI - 10.1039/a809129c
Subject(s) - chemistry , phosphine , saddle point , reaction rate constant , kinetics , spin (aerodynamics) , thermodynamics , physics , biochemistry , geometry , mathematics , quantum mechanics , catalysis
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