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Isolation of a nearly eclipsed chiral rotamer of 1,2-dichloroethane as an inclusion crystal with a chiral host compound
Author(s) -
Fumio Toda,
Koichi Tanaka,
Reiko Kuroda
Publication year - 1997
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/a702333b
Subject(s) - 1,2 dichloroethane , conformational isomerism , chemistry , host (biology) , crystal (programming language) , crystallography , inclusion (mineral) , stereochemistry , molecule , organic chemistry , biology , mineralogy , ecology , catalysis , computer science , programming language
A nearly eclipsed chiral rotamer of 1,2-dichloroethane has been isolated in a pure state as an inclusion complex crystal with the chiral host compound, (S)-(-)-2-bromo-3,3a,8-triphenyl-1,3a-dihydrocyclopenta[ a]inden-1-one and an X-ray crystal structure of the complex has been studied.

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