Ruthenium(iii)-promoted oxidative dimerization of aniline to N-phenyl-1,2-phenylenediimine. Definitive proof for the template reaction
Author(s) -
Kedar Nath Mitra,
Partha Majumdar,
ShieMing Peng,
Alfonso Castine ̃iras,
Sreebrata Goswami
Publication year - 1997
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/a702047c
Subject(s) - aniline , ruthenium , oxidative phosphorylation , chemistry , catalysis , combinatorial chemistry , polymer chemistry , medicinal chemistry , photochemistry , organic chemistry , biochemistry
Two novel examples of ruthenium-promoted oxidative ortho-dimerization of aniline are described which demonstrate that the dimerization reaction proceeds via coordination of anilines to the metal ion.
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