An assessment of 40 Ar‐ 39 Ar dating of incompletely degassed xenoliths

The possibility of measuring the age of eruption of Pleistocene lavas by 40 Ar‐ 39 Ar analysis of entrapped ancient potassic xenoliths is demonstrated by a study of model systems. Upon inclusion in the hot magma such xenoliths are commonly only partially degassed of radiogenic 40 Ar which has accumulated in them since their original crystallization. The residual 40 Ar will increase the apparent K/Ar age of the xenolith. However, if a xenolith is of Cretaceous age or younger, then a plateau in its 40 Ar‐ 39 Ar age spectrum giving the age of eruption is expected to extend over 25–50% of the total 39 Ar released if degassing of the xenolith in the magma exceeded 90% and if the phases in the xenolith are characterized by sufficiently different diffusion dimensions or activation energies. If diffusion was from a bimodal population of spheres, then the radii must differ by a factor of 10 or more (or the diffusion coefficients by a factor of 100 or more); or if the spheres were equal in size (and in diffusion coefficients), then the activation energies must differ by a factor of at least 1.5. That such requirements may be realized in real xenoliths containing K‐feldspars is expected from published activation energies for microcline and from data determined on a granitic xenolith which was degassed in an early Pleistocene basalt flow. The experimental results appear to establish that old xenoliths may contain Ar in distinctive phases which degas at sufficiently different temperatures as to permit determination of the age of degassing or eruption.