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Influences of biomass burning during the Transport and Chemical Evolution Over the Pacific (TRACE‐P) experiment identified by the regional chemical transport model
Author(s) -
Tang Youhua,
Carmichael Gregory R.,
Woo JungHun,
Thongboonchoo Narisara,
Kurata Gakuji,
Uno Itsushi,
Streets David G.,
Blake Donald R.,
Weber Rodney J.,
Talbot Robert W.,
Kondo Yutaka,
Singh Hanwant B.,
Wang Tao
Publication year - 2003
Publication title -
journal of geophysical research: atmospheres
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.67
H-Index - 298
eISSN - 2156-2202
pISSN - 0148-0227
DOI - 10.1029/2002jd003110
Subject(s) - trace gas , biomass burning , environmental science , biomass (ecology) , chemical transport model , plume , ozone , outflow , atmospheric sciences , aerosol , air mass (solar energy) , chemical evolution , environmental chemistry , chemistry , meteorology , troposphere , geology , oceanography , geography , physics , stars , boundary layer , astronomy , thermodynamics
Using a regional chemical transport model, STEM 2K1, and the emission inventory for the Transport and Chemical Evolution Over the Pacific (TRACE‐P) period [ Woo et al. , Streets et al. , this issue], we successfully simulated important features of the biomass burning (BB) CO outflow. Simulated results agree well with the TRACE‐P aircraft measurements and Thailand surface observations. On the basis of sensitivity studies with and without biomass emissions, we identified nine flight segments that are affected by biomass plumes during the TRACE‐P period and compared the characteristics of the BB air masses with the other air masses. The BB air masses emitted from Southeast Asia contain relatively high HCN (ΔHCN/ΔCO ∼ 0.0015) and potassium (ΔK + /ΔCO ∼ 0.0038) but very low NO y (ΔNO y /ΔCO ∼ 0.005) mixing ratios, which may be associated with the special burning condition in this region. The biomass burning air masses have high ozone production efficiency. The observed ΔO 3 /ΔNO z values were ∼17 in biomass events and 1.7 in other events. The BB influence on the trace gas distributions can be divided into two categories: the influence through direct reactions and the influence caused by BB aerosols changing J values. These two influences are discussed for the BB‐affected TRACE‐P flights and for east Asia. The BB influences on chemical species are not only determined by the BB plume intensity but also by the ambient environment caused by other emissions. In Southeast Asia, where the biogenic emissions are very strong, the OH background concentration is low, and the BB gas‐phase compounds mainly contribute to OH production. Arranged in the sensitivity to the J value change caused by BB aerosols, we have OH > HO 2 > HCHO > O 3 when evaluated on a regional average. Averaged over March, the biomass burning net influence is as high as 50% for OH, 40% for HO 2 , 60% for HCHO, and 10 ppbv for O 3 for the layers below 1 km.

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