Open AccessNeodymium budget in the modern ocean and paleo‐oceanographic implications
Author(s) -
Tachikawa K.,
Athias V.,
Jeandel C.
Publication year - 2003
Publication title -
journal of geophysical research: oceans
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.67
H-Index - 298
eISSN - 2156-2202
pISSN - 0148-0227
DOI - 10.1029/1999jc000285
Subject(s) - authigenic , geology , oceanography , interglacial , flux (metallurgy) , glacial period , deep sea , north atlantic deep water , water mass , ocean current , ocean general circulation model , environmental science , climatology , thermohaline circulation , climate change , general circulation model , mineralogy , materials science , diagenesis , geomorphology , metallurgy
The oceanic Nd budget is calculated using a steady state 10‐box model and a compilation of field data. This is the first attempt to propose consistent estimates of the Nd fluxes entering the ocean, as well as indicating possible Nd sources and the proportion of Nd fluxes exchanged between dissolved and particulate fractions. With presently available Nd data the best estimates give a total Nd influx of 9 × 10 9 g/yr, which leads to an oceanic Nd residence time of 500 years. From modeling tests we suggest that the authigenic Nd scavenged by particulates is 100% remineralized in the deep ocean. The total exchanged Nd flux may be as high as 2 × 10 10 g/yr. The ε Nd(0) values of the influxes are −22, −11, +1, and −4 for the North Atlantic, surface Atlantic, North Pacific, and surface Indo‐Pacific regions, respectively. Atmospheric and riverine Nd fluxes are insufficient to explain the magnitude and regional variability of calculated Nd influxes and ε Nd(0) . We propose continental margins as an additional source supplying Nd to the ocean. Using the model calibrated for Nd, we examine the sensitivity of deep water ε Nd(0) to variations of Nd inputs to the ocean. Deep water Nd concentrations and ε Nd(0) vary with the changes in Nd influxes and their ε Nd(0) . As Nd sources to the ocean may change during glacial/interglacial periods, the ε Nd(0) shifts recorded in ferromanganese nodules and crusts do not necessarily reflect changes in paleoceanic circulation. The effects of continental erosion should be considered in reconstructing patterns of ocean circulation using Nd isotopes.