Open AccessCarbene Transfer between Transition-Metal Ions
Author(s) -
ShiuhTzung Liu,
Tung-Ying Hsieh,
GeneHsiang Lee,
ShieMing Peng
Publication year - 1998
Publication title -
organometallics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.231
H-Index - 172
eISSN - 1520-6041
pISSN - 0276-7333
DOI - 10.1021/om9709897
Subject(s) - carbene , chemistry , transition metal , metal , ion , transition metal carbene complex , medicinal chemistry , photochemistry , polymer chemistry , catalysis , organic chemistry
A carbene transfer reaction between transition-metal complexes is reported. Carbene complexes of Pd(II), Pt(II), Rh(I), and Au(I) are formed via the reaction = W, Mo, Cr; R = Et, allyl) with (PhCN)2PdCl2, (PhCN)2PtCl2, [(CO)2RhCl]2, and (Me2S)AuCl. The complexes prepared in high yields via a carbene transfer pathway. The X-ray structures (4) are reported.
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