A New Scorpionate Ligand: Tris(4,4-dimethyl-2-oxazolinyl)borate and Its Zirconium(IV) Complexes | Zendy

James F. Dunne | Zendy; Jiachun Su | Zendy; Arkady Ellern | Zendy; Aaron D. Sadow | Zendy

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A New Scorpionate Ligand: Tris(4,4-dimethyl-2-oxazolinyl)borate and Its Zirconium(IV) Complexes

Author(s) -

James F. Dunne,

Jiachun Su,

Arkady Ellern,

Aaron D. Sadow

Publication year - 2008

Publication title -

organometallics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.231

H-Index - 172

eISSN - 1520-6041

pISSN - 0276-7333

DOI - 10.1021/om800252p

Subject(s) - chemistry , steric effects , oxazoline , tris , ligand (biochemistry) , boron , zirconium , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry , catalysis , biochemistry , receptor

The first example of a new class of oxazoline-based scorpionate ligand, tris(4,4-dimethyl-2-oxazolinyl)phenyl borate, [ToM]−, is prepared by reaction of 2-lithio-4,4-dimethyl-2-oxazolide and 0.3 equiv of dichlorophenylborane. The steric bulk of this ligand is greater than that of tris(3,5-Me2-pyrazolyl)borate (Tp*), as quantified by comparison of solid angles of crystallographically characterized zirconium(IV) complexes.

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