Unprecedented Reduction of 2,2′-Bipyrimidine in a One-Pot Synthesis of Neutral Rhenium(I)-Based Molecular Rectangles | Zendy

JingYun Wu | Zendy; Pounraj Thanasekaran | Zendy; Yiwei Cheng | Zendy; ChungChou Lee | Zendy; B. Manimaran | Zendy; T. Rajendran | Zendy; Rong-Tang Liao | Zendy; GeneHsiang Lee | Zendy; ShieMing Peng | Zendy; KuangLieh Lu | Zendy

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Unprecedented Reduction of 2,2′-Bipyrimidine in a One-Pot Synthesis of Neutral Rhenium(I)-Based Molecular Rectangles

Author(s) -

JingYun Wu,

Pounraj Thanasekaran,

Yiwei Cheng,

ChungChou Lee,

B. Manimaran,

T. Rajendran,

Rong-Tang Liao,

GeneHsiang Lee,

ShieMing Peng,

KuangLieh Lu

Publication year - 2008

Publication title -

organometallics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.231

H-Index - 172

eISSN - 1520-6041

pISSN - 0276-7333

DOI - 10.1021/om700873x

Subject(s) - chemistry , rhenium , bimetallic strip , moiety , electrochemistry , photoluminescence , single crystal , crystal structure , proton nmr , crystallography , stereochemistry , organic chemistry , electrode , catalysis , physics , optics

An unprecedented partial reduction of 2,2′-bipyrimidine (bpym) occurred, affording the H6bpym2− moiety, during the one-pot self-assembly of neutral Re(I)-based molecular rectangles and bimetallic products under solvothermal conditions. Their structures were unambiguously characterized by 1H NMR and single-crystal X-ray diffraction analyses, and their electrochemical, electronic absorption, and photoluminescent properties were studied. The reaction pathway was also investigated.

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