Open AccessTemplated Rearrangement of Silylated Benzoxazolin-2-ones: A Novel Tridentate (ONO)2- Chelating Ligand System
Author(s) -
Jörg Wagler,
Anthony F. Hill
Publication year - 2007
Publication title -
organometallics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.231
H-Index - 172
eISSN - 1520-6041
pISSN - 0276-7333
DOI - 10.1021/om700416b
Subject(s) - chemistry , chelation , silane , ligand (biochemistry) , silicon , bearing (navigation) , polymer chemistry , stereochemistry , medicinal chemistry , inorganic chemistry , organic chemistry , receptor , biochemistry , cartography , geography
The reaction of phenyltrichlorosilane with benzoxazolin-2-one gives rise to phenyltris(benzoxazolin-2-on-1-yl)silane, which thermally rearranges to a pentacoordinate silicon compound bearing a novel (ONO) tridentate chelating ligand with interesting coordination properties.
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