Ruthenium Carbonyl Complexes Bearing Secondary Phosphine Oxides and Phosphinous Acids: Synthesis, Characterization, and Application in Catalysis | Zendy

Lionel V. Graux | Zendy; Michel Giorgi | Zendy; Gérard Buono | Zendy; Hervé Clavier | Zendy

Open Access

Ruthenium Carbonyl Complexes Bearing Secondary Phosphine Oxides and Phosphinous Acids: Synthesis, Characterization, and Application in Catalysis

Author(s) -

Lionel V. Graux,

Michel Giorgi,

Gérard Buono,

Hervé Clavier

Publication year - 2015

Publication title -

organometallics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.231

H-Index - 172

eISSN - 1520-6041

pISSN - 0276-7333

DOI - 10.1021/om501300p

Subject(s) - chemistry , ruthenium , cycloisomerization , phosphine , catalysis , phosphine oxide , ligand (biochemistry) , organic chemistry , biochemistry , receptor

International audienceTwo series of ruthenium carbonyl complexes bearing either one secondary phosphine oxide ligand or two phosphinous acids have been synthesized and characterized. The catalytic behavior of these complexes has been then investigated for the cycloisomerization of arenynes. This study highlighted a strong relationship between ligands’ and substrates’ substructures

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