Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors | Zendy

Miles W. Johnson | Zendy; Antonio G. DiPasquale | Zendy; Robert G. Bergman | Zendy; F. Dean Toste | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors

Author(s) -

Miles W. Johnson,

Antonio G. DiPasquale,

Robert G. Bergman,

F. Dean Toste

Publication year - 2014

Publication title -

organometallics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.231

H-Index - 172

eISSN - 1520-6041

pISSN - 0276-7333

DOI - 10.1021/om500663m

Subject(s) - chemistry , pincer movement , heteroatom , reactivity (psychology) , pyridine , electrochemistry , carboxylate , ligand (biochemistry) , pincer ligand , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , catalysis , ring (chemistry) , receptor , electrode , medicine , biochemistry , alternative medicine , pathology

A series of gold(III) complexes supported by pyridine-based bis(amidate), bis(carboxylate), and bis(iminothiolate) substituents is reported. These compounds represent rare examples of pincer-ligated gold(III) centers with multiple anionic heteroaom donors. Reactivity and electrochemical studies demonstrate the stability of these compounds and the marked difference in reduction potentials with varying ligand scaffolds.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research