Increased Yields and Simplified Purification with a Second-Generation Cobalt Catalyst for the Oxidative Formation of trans-THF Rings | Zendy

Cory Palmer | Zendy; Nicholas A. Morra | Zendy; Andrew C. Stevens | Zendy; Barbora Bajtos | Zendy; Ben P. Machin | Zendy; Brian L. Pagenkopf | Zendy

Open Access

Increased Yields and Simplified Purification with a Second-Generation Cobalt Catalyst for the Oxidative Formation of trans-THF Rings

Author(s) -

Cory Palmer,

Nicholas A. Morra,

Andrew C. Stevens,

Barbora Bajtos,

Ben P. Machin,

Brian L. Pagenkopf

Publication year - 2009

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/ol9023375

Subject(s) - catalysis , chemistry , cobalt , oxidative phosphorylation , combinatorial chemistry , organic chemistry , biochemistry

The synthesis of a second-generation cobalt catalyst for the formation of trans-THF products via the Mukaiyama aerobic oxidative cyclization is reported. Two procedures have been developed with the new water-soluble catalyst that give superior yields and greatly simplify purification compared to the previous catalysts.

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