A Biomimetic Electrocatalytic System for the Atom-Economical Chemoselective Synthesis of Secondary Amines | Zendy

Martine Largeron | Zendy; MauriceBernard Fleury | Zendy

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A Biomimetic Electrocatalytic System for the Atom-Economical Chemoselective Synthesis of Secondary Amines

Author(s) -

Martine Largeron,

MauriceBernard Fleury

Publication year - 2009

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/ol802885b

Subject(s) - chemistry , primary (astronomy) , imine , combinatorial chemistry , ammonia , amine gas treating , atom (system on chip) , sequence (biology) , organic chemistry , catalysis , biochemistry , physics , astronomy , computer science , embedded system

A facile one-pot oxidation-imine formation-reduction route to secondary amines can be achieved electrolytically from primary amines. This atom-economical 1(ox)-mediated sequence, leaving ammonia as the sole byproduct, allows the rapid chemoselective synthesis of secondary amines, at both ambient temperature and pressure.

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