Base-Promoted Reactions of Dichlorocarbene Adducts of Cyclic Enamines: A New Route to Annulated Pyrroles
Author(s) -
Alex C. Bissember,
A.T. Phillis,
Martin G. Banwell,
Anthony C. Willis
Publication year - 2007
Publication title -
organic letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.94
H-Index - 239
eISSN - 1523-7060
pISSN - 1523-7052
DOI - 10.1021/ol7021774
Subject(s) - dichlorocarbene , chemistry , adduct , base (topology) , organic chemistry , combinatorial chemistry , mathematical analysis , mathematics
Treatment of the gem-dihalogenocyclopropanes 1-5 with potassium tert-butoxide or LDA results in the formation of the corresponding and annulated pyrroles 13-17, respectively.
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