Caeruleanone A, a Rotenoid with a New Arrangement of the D-Ring from the Fruits of Millettia caerulea | Zendy

Lynette Bueno Pérez | Zendy; Pan Li | Zendy; Ulyana Muñoz Acuña | Zendy; Jie Li | Zendy; HeeByung Chai | Zendy; Judith C. Gallucci | Zendy; Tran Ngoc Ninh | Zendy; Esperanza J. Carcache de Blanco | Zendy; Djaja D. Soejarto | Zendy; A. Douglas Kinghorn | Zendy

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Caeruleanone A, a Rotenoid with a New Arrangement of the D-Ring from the Fruits of Millettia caerulea

Author(s) -

Lynette Bueno Pérez,

Pan Li,

Ulyana Muñoz Acuña,

Jie Li,

HeeByung Chai,

Judith C. Gallucci,

Tran Ngoc Ninh,

Esperanza J. Carcache de Blanco,

Djaja D. Soejarto,

A. Douglas Kinghorn

Publication year - 2014

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/ol500266z

Subject(s) - chemistry , caerulea , stereochemistry , ring (chemistry) , botany , organic chemistry , biology

Caeruleanone A (1), a novel rotenoid with an unprecedented arrangement of the D-ring, was isolated with another two new analogues, caeruleanones B (2) and C (3), together with 11 known rotenoids from the fruits of Millettia caerulea. The structures of the new compounds were determined by spectroscopic data analysis, with that of 1 being confirmed by single-crystal X-ray diffraction. Compounds 2 and 3 displayed potent mitochondrial transmembrane potential inhibitory and quinone reductase induction activities.

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