Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives | Zendy

Christiane Wuensch | Zendy; Silvia M. Glueck | Zendy; Johannes Gross | Zendy; Dominik Koszelewski | Zendy; Markus Schöber | Zendy; Kurt Faber | Zendy

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Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives

Author(s) -

Christiane Wuensch,

Silvia M. Glueck,

Johannes Gross,

Dominik Koszelewski,

Markus Schöber,

Kurt Faber

Publication year - 2012

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/ol300385k

Subject(s) - carboxylation , chemistry , regioselectivity , phenol , organic chemistry , phenols , cinnamic acid , benzoic acid , enzyme , carboxylic acid , catalysis

The enzymatic carboxylation of phenol and styrene derivatives using (de)carboxylases in carbonate buffer proceeded in a highly regioselective fashion: Benzoic acid (de)carboxylases selectively formed o-hydroxybenzoic acid derivatives, phenolic acid (de)carboxylases selectively acted at the β-carbon atom of styrenes forming (E)-cinnamic acids.

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