Open AccessRing Cleavage and Successive Aldol Reaction of 3-[(Trialkylsilyl)methyl]cyclobutanones
Author(s) -
Junichi Matsuo,
K. HARADA,
Mizuki Kawano,
Ryosuke Okuno,
Hiroyuki Ishibashi
Publication year - 2011
Publication title -
organic letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.94
H-Index - 239
eISSN - 1523-7060
pISSN - 1523-7052
DOI - 10.1021/ol202424p
Subject(s) - aldol reaction , cleavage (geology) , social media , computer science , library science , chemistry , world wide web , information retrieval , engineering , organic chemistry , geotechnical engineering , fracture (geology) , catalysis
3-[(Trialkylsilyl)methyl]cyclobutanones reacted with aldehydes by activation with titanium(IV) chloride to give acyclic β,γ-unsaturated β'-hydroxyketones.
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