A Redox-Gated Slow-Fast-Stop Molecular Rotor | Zendy

Cheng-Hua Yang | Zendy; Ch. Prabhakar | Zendy; ShouLing Huang | Zendy; YingChih Lin | Zendy; Wei Tan | Zendy; Nimesh C. Misra | Zendy; WeiTing Sun | Zendy; JyeShane Yang | Zendy

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A Redox-Gated Slow-Fast-Stop Molecular Rotor

Author(s) -

Cheng-Hua Yang,

Ch. Prabhakar,

ShouLing Huang,

YingChih Lin,

Wei Tan,

Nimesh C. Misra,

WeiTing Sun,

JyeShane Yang

Publication year - 2011

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/ol202356t

Subject(s) - chemistry , redox , rotor (electric) , amine gas treating , radical ion , rotation (mathematics) , photochemistry , computational chemistry , chemical physics , ion , inorganic chemistry , organic chemistry , quantum mechanics , physics , geometry , mathematics

A pentiptycene-derived p-phenylenediamine mimics a molecular double-rotor system that displays redox-dependent rotation rates for the amino rotors about the pentiptycene-amine C-N bond. The rotation is accelerated in the radical cation state but stopped in the di(radical cation) state. Electronic interplay of the two rotors is also discussed.

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