Open AccessGlycoside Bond Formation via Acid–Base Catalysis
Author(s) -
Amit Kumar,
Vipin Kumar,
Ravindra T. Dere,
Richard R. Schmidt
Publication year - 2011
Publication title -
organic letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.94
H-Index - 239
eISSN - 1523-7060
pISSN - 1523-7052
DOI - 10.1021/ol201231v
Subject(s) - chemistry , base (topology) , catalysis , glycoside , stereochemistry , combinatorial chemistry , organic chemistry , mathematical analysis , mathematics
Acid-base catalyzed glycosyl donor and then glycosyl acceptor activation with phenylboron difluoride or diphenylboron fluoride permits hydrogen bond mediated intramolecular S(N)2-type glycosidation in generally high anomeric selectivity.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom