Facile Synthesis of 5,10,15-Hexaaryl Truxenes: Structure and Properties | Zendy

Min-Tzu Kao | Zendy; Jia-Hong Chen | Zendy; Yingying Chu | Zendy; KuoPi Tseng | Zendy; ChiaHuei Hsu | Zendy; KenTsung Wong | Zendy; CheWei Chang | Zendy; ChaoPing Hsu | Zendy; YiHung Liu | Zendy

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Facile Synthesis of 5,10,15-Hexaaryl Truxenes: Structure and Properties

Author(s) -

Min-Tzu Kao,

Jia-Hong Chen,

Yingying Chu,

KuoPi Tseng,

ChiaHuei Hsu,

KenTsung Wong,

CheWei Chang,

ChaoPing Hsu,

YiHung Liu

Publication year - 2011

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/ol200227w

Subject(s) - chemistry , aryl , core (optical fiber) , molecule , diffraction , rigidity (electromagnetism) , crystallography , stereochemistry , organic chemistry , materials science , alkyl , physics , optics , composite material

A new synthesis of 5,10,15-hexaaryltruxene derivatives has been developed. Experimental observations and theoretical calculations confirmed that the presence of aryl substituents on the sp(3)-hybridized bridge carbon atoms had an effect on the photophysical properties of the truxene core. Interestingly, the cage compound 11 possessing a distorted truxene core was verified by X-ray diffraction analysis; the influence of the peripheral aryl substituents on the photophysical properties of the truxene core was diminished because of its molecular rigidity.

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