ExTTF-Based Dyes Absorbing over the Whole Visible Spectrum | Zendy

PierreAntoine Bouit | Zendy; Carmen Villegas | Zendy; Juan Luis Delgado | Zendy; Pedro M. Viruela | Zendy; Rosendo PouAmérigo | Zendy; Enrique Ortı́ | Zendy; Nazario Martı́n | Zendy

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ExTTF-Based Dyes Absorbing over the Whole Visible Spectrum

Author(s) -

PierreAntoine Bouit,

Carmen Villegas,

Juan Luis Delgado,

Pedro M. Viruela,

Rosendo PouAmérigo,

Enrique Ortı́,

Nazario Martı́n

Publication year - 2011

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/ol102845m

Subject(s) - tetrathiafulvalene , chemistry , visible spectrum , acceptor , photochemistry , optoelectronics , absorption (acoustics) , absorption spectroscopy , electrochemistry , infrared , photovoltaic system , nanotechnology , molecule , optics , electrode , organic chemistry , materials science , physics , ecology , biology , condensed matter physics

New push-pull dyes featuring π-extended tetrathiafulvalene (exTTF) as the donor group and tricyanofuran (TCF) as the acceptor group were synthesized and characterized. Their broad absorption covers the entire visible spectral range and enters the near-infrared region. Electrochemistry and theoretical calculations provided an understanding of these singular electronic properties. The new dyes are appealing candidates as light harvesters in photovoltaic devices.

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